Main article: Extraction (fragrance)
Distillation
Today, most common essential oils, such as lavender, peppermint, and eucalyptus, are distilled. Raw plant material, consisting of the flowers, leaves, wood, bark, roots, seeds, or peel, is put into an alembic (distillation apparatus) over water. As the water is heated the steam passes through the plant material, vaporizing the volatile compounds. The vapors flow through a coil where they condense back to liquid, which is then collected in the receiving vessel.
Most oils are distilled in a single process. One exception is Ylang-ylang (Cananga odorata), which takes 22 hours to complete through a fractional distillation.
The recondensed water is referred to as a hydrosol, hydrolat, herbal distillate or plant water essence, which may be sold as another fragrant product. Popular hydrosols include rose water, lavender water, lemon balm, clary sage and orange blossom water. The use of herbal distillates in cosmetics is increasing. Some plant hydrosols have unpleasant smells and are therefore not sold.
Expression
Most citrus peel oils are expressed mechanically, or cold-pressed. Due to the relatively large quantities of oil in citrus peel and low cost to grow and harvest the raw materials, citrus-fruit oils are cheaper than most other essential oils. Lemon or sweet orange oils that are obtained as by-products of the citrus industry are even cheaper.
Prior to the discovery of distillation, all essential oils were extracted by pressing.
Solvent extraction
Most flowers contain too little volatile oil to undergo expression and their chemical components are too delicate and easily denatured by the high heat used in steam distillation. Instead, a solvent such as hexane or supercritical carbon dioxide is used to extract the oils. Extracts from hexane and other hydrophobic solvent are called concretes, which are a mixture of essential oil, waxes, resins, and other lipophilic (oil soluble) plant material.
Although highly fragrant, concretes contain large quantities of non-fragrant waxes and resins. As such another solvent, often ethyl alcohol, which only dissolves the fragrant low-molecular weight compounds, is used to extract the fragrant oil from the concrete. The alcohol is removed by a second distillation, leaving behind the absolute.
Supercritical carbon dioxide is used as a solvent in supercritical fluid extraction. This method has many benefits, including avoiding petrochemical residues in the product and the loss of some "top notes" when steam distillation is used. It does not yield an absolute directly. The supercritical carbon dioxide will extract both the waxes and the essential oils that make up the concrete. Subsequent processing with liquid carbon dioxide, achieved in the same extractor by merely lowering the extraction temperature, will separate the waxes from the essential oils. This lower temperature process prevents the decomposition and denaturing of compounds. When the extraction is complete, the pressure is reduced to ambient and the carbon dioxide reverts back to a gas, leaving no residue. An animated presentation describing the process is available for viewing.
Supercritical carbon dioxide is also used for making decaffeinated coffee. However, although it uses the same basic principles it is a different process because of the difference in scale.
Production quantities
Estimates of total production of essential oils are difficult to obtain. One estimate, compiled from data in 1989, 1990 and 1994 from various sources gives the following total production, in tonnes, of essential oils for which more than 1,000 tonnes were produced.
Oil Tonnes
Sweet orange 12,000
Mentha arvensis 4,800
Peppermint 3,200
Cedarwood 2,600
Lemon 2,300
Eucalyptus globulus 2,070
Litsea cubeba 2,000
Clove (leaf) 2,000
Spearmint 1,300
Use in aromatherapy
Aromatherapy is a form of alternative medicine, in which healing effects are ascribed to the aromatic compounds in essential oils and other plant extracts. Many common essential oils have medicinal properties that have been applied in folk medicine since ancient times and are still widely used today. For example, many essential oils have antiseptic properties.[3] Many are also claimed to have an uplifting effect on the mind.
Dilution
Essential oils are usually lipophilic (literally: "oil-loving") compounds that usually are not miscible with water. Instead, they can be diluted in solvents like pure ethanol (alcohol), polyethylene glycol, or oils.